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Tuesday, July 28, 2020 | History

1 edition of chemistry of the nitro and nitroso groups found in the catalog.

chemistry of the nitro and nitroso groups

chemistry of the nitro and nitroso groups

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Published by Interscience in New York, London .
Written in English


Edition Notes

Statementedited by Henry Feuer. Pt.1.
SeriesThe chemistry of functional groups
ContributionsFeuer, Henry, 1912-
ID Numbers
Open LibraryOL14335478M

  The chemistry of amino, nitroso, nitro, and related groups The chemistry of amino, nitroso, nitro, and related groups by Saul Patai Published by Wiley in Chichester [West Sussex], New York. The organic compounds that have one or more groups that are nitro functional (-NO 2) are called nitro compounds. Simply put, any group of chemical compounds that has the nitro group (-O-N=O) becoming a member of the structure of molecules is a nitro compound. Certain examples include organic substances that have the covalent bond of a nitrogen.

Nitro compounds are organic compounds that contain one or more nitro functional groups (−N O 2).The nitro group is one of the most common explosophores (functional group that makes a compound explosive) used globally. The nitro group is also strongly e of this property, C−H bonds alpha (adjacent) to the nitro group can be acidic. In book: Amino, Nitroso, Nitro and Related Groups, pp An important objective of applied nature in polynitroaromatics chemistry is the development of techniques for selective reduction.

The reduction of nitro compounds are chemical reactions of wide interest in organic chemistry. The conversion can be effected by many reagents. The nitro group was one of the first functional groups to be and aryl nitro compounds behave differently. Most useful is the reduction of aryl nitro . A simple gasometric micro-method is described for the rapid determination of the amino group in aromatic amines, -amino-acids and carboxamides. The method is based on a deamination reaction whereby 1 mol of nitrous oxide is liberated per mole of compound. Anilides are first hydrolysed with hydrochloric acid, and ni.


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Chemistry of the nitro and nitroso groups Download PDF EPUB FB2

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An illustration of a " floppy disk. Software. An illustration of two photographs. Full text of "The Chemistry Of The Nitro And Nitroso Groups P. : Chemistry of the Nitro and Nitroso Groups Part 2 (Chemistry of Functional Groups) (): Feuer, Henry: Books. Is the chemistry of the nitro and nitroso groups your chemistry of the nitro and nitroso groups book book now.

That's true; you are really a good reader. This is a perfect book that comes from great author to share with you. The book offers the best experience and lesson to take, not only take, but also learn. English Long-awaited "The chemistry of the nitro and nitroso groups, part 1", from Patai's book series.

Scans of rather good quality; pages without content were skipped. Description Organic compounds containing Nitrogen are of outstanding importance in biochemistry and in environmental systems. This volume gives a sound introduction into the physical chemistry of amino, nitroso, nitro and related functional groups.

These species include nitro (R NO 2), organic nitrates (R NO 2), organic nitrites (R O N O), and nitroso groups. The N O stretching vibrations result in strong IR bands and generally moderate Raman bands.

Aliphatic and aromatic nitro compounds have two IR strong bands between and cm −1 and – cm −1. Biochemistry and Pharmacology of the Nitro and Nitroso Groups (Pages: ). Nitroso refers to a functional group in organic chemistry which has the NO group attached to an organic such, various nitroso groups can be categorized as C-nitroso compounds (e.g., nitrosoalkanes; R−N=O), S-nitroso compounds (nitrosothiols; RS−N=O), N-nitroso compounds (e.g., nitrosamines, R 1 N(−R 2)−N=O), and O-nitroso compounds (alkyl nitrites; RO−N=O).

Alternatively, the amino group of 4-nitrobenzenamine can be oxidized to a nitro group by trifluoroperoxyacetic acid. In these syntheses, \(\ce{N}\)-phenylethanamide is nitrated in preference to benzenamine itself because, not only is benzenamine easily oxidized by nitric acid, but the nitration reaction leads to extensive 3-substitution as the.

The chemistry of the nitro and nitroso groups Edited by HENRY FEUER Purdue University Lafayette, Indiana Part 2 INTERSCIENCE PUBLISHERS a division Joh ofn Wiley & Sons NEW YORK LONDON SYDNEY TORONTO.

CHAPTER 2 Directing effects of the nitro group in. About this book The most useful reactions of organonitro compounds in organic synthesis Compounds containing nitro groups are useful intermediates for the synthesis of natural products and other complex organic molecules. Additional Physical Format: Online version: Feuer, Henry, Chemistry of the nitro and nitroso groups.

New York, Interscience Publishers,   : The Chemistry of Amino, Nitroso, Nitro and Related Groups, Supplement F2: Vol. 1, Pts. 1 & 2 (): Patai, Saul, Rappoport, Zvi: Books. Edited by Saul Patai, John Wiley & Sons, Ltd., – p. The material reviewed in the present volume Supplement F2: The chemistry of amino, nitroso, nitro and related groups has been previously covered in the following books in the Chemistry of the Functional Groups series The chemistry of the amino group () The chemistry of the nitro and nitroso groups, Parts 1 and 2 ( Ebooks list page: ; [PDF] The Chemistry of Amino, Nitroso, Nitro and Related Groups, Supplement F2: Vol.

1, Pts. 1 & 2; Supplement F2: The Chemistry of Amino, Nitroso, Nitro and Related 1 [Repost] Chemistry of Amino, Nitroso, Nitro and Related Groups; Superstrings and Related Matters: Proceedings of the ICTP Spring. Owing to their importance, the second edition of the Special Issue “Recent Synthetic Aspects on the Chemistry of Nitro, Nitroso and Amino Compounds” aims to highlight the more recent advances on the chemistry of these nitrogen derivatives.

Chemistry of the Nitro and Nitroso Groups Book Title:Chemistry of the Nitro and Nitroso Groups This twopart set covers all aspects of the chemistry of one of the functional groups. Discussions on. Chemistry of nitro groups and nitro compounds has long been intensively studied.

Despite their long history, new reactions and methodologies are still being found today. This is due to the diverse reactivity of the nitro group. The importance of nitro chemistry will continue to increase in the future in terms of elaborate synthesis.

In this article, we will take a walk through the recent. Nitro groups in the homocyclic ring of 1,2-benzisoxazoles have been reduced to the corresponding amino groups without opening of the isoxazole nucleus. SnCl 2 /HCl and Adam’s catalyst/H 2 have both proved effective in this respect.

Similar behavior was observed for nitro groups in the isomeric 2,1-benzisoxazoles 〈67AHC(8), pp.〉. Normally, the nitroso compound is further reduced rapidly and cannot be isolated during the reduction in acidic solution.

On the other hand, reduction of aromatic nitro compounds in alkaline solution give rise to competing reactions which significantly slow down further reduction. Under these conditions the nitroso compounds can be isolated.

Nitro compound, any of a family of chemical compounds in which the nitro group (―O―N=O) forms part of the molecular structure. The most common examples are organic substances in which a carbon atom is linked by a covalent bond to the nitrogen atom of the nitro group.

Nitro compounds are polar, and those with no other chemically reactive grouping are colourless or pale yellow liquids that.Molecular mechanics calculations / Pinchas Aped and Hanoch Senderowitz --Structural chemistry / Salvatore Sorriso --Chiroptical properties of amino compounds / Howard E.

Smith --Photoelectron spectra of amines, nitroso and nitro compounds / Paul Rademacher --The chemistry of ionized, protonated and cationated amines in the gas phase / Richard D.The ambident nature of the nitro group makes it a very versatile reagent.

Reduction General In principle the reduction of nitro compounds should follow the path; The reduction of nitroso groups is generally more easily achieved but the nitro group can be reduced in a number of different ways; Photochemically.

Metal/H + Reactions.